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TITLE Photochromism - Molecules and Systems
ISBN 0-444-51322-1
URL Hyperlink
AUTHORS Durr, H.;Bouas-Laurent, H.
EDITION
VOLUME
PAGES 1044
IMPRINT Elsevier
BINDING HC
DESCRIPTION Hardbound. Photochromism is simply defined as the light induced reversible change of colour. It is both of great basic interest and of high application potential and brings together scientists from a variety of domains in chemistry, physics and engineering, as stated in the foreword provided by Jean-Marie Lehn. The field has developed rapidly during the past decade as a result of attempts to improve the established materials and to discover new devices for applications.

As photochromism bridges molecular, supramolecular and solid state chemistry, as well as organic, inorganic and physical chemistry, such a treatment requires a multidisciplinary approach and a broad presentation. The first edition (1990) provided an enormous amount of new concepts and data, such as the presentation of main families based on the pericyclic reaction mechanism, the review of new families, some bimolecular photocycloadditions and some promising systems. This work beca
PUBDATE 01-Mar-03
USD 210
Euro 210
REVIEW
TOC http://www.elsevier.com/inca/publications/misc/672882toc.rtfFull Table of Contents
Section and chapter headings. General Introduction (H. Dürr)

Photophysical, Photochemical and Photokinetic Properties of Photochromic Systems

Photophysical, photochemical and photokinetic properties of photochromic systems (G. Gauglitz).

Photochromism Based on "E-Z" Isomerization of Double Bonds

CIS-trans isomerization of C=C double bonds (J. Saltiel, Y.-P. Sun).
Azo compounds (H. Rau).


Photochromism Based on Pericyclic Reactions: Electrocyclization Reactions


4n systems based on l,3-electrocyclization (C. Schulz, H. Dürr).
4n+2 systems based on 1,5-electrocyclization (H. Dürr).
4n+2 systems: molecules derived from Z-Hexa-1,3,5-Triene/ Cyclohexa- 1,3-Diene (W.H.Laarhoven).
4n+2 systems: spiropyrans (R. Guglielmetti).
4n+2 systems: fulgides (J. Whittal).
4n+2 systems: spirooxazines (N.Y.C. Chu).
4n and 4n+2 systems (n>2) based on 1,7- and l,10-electrocyclization (H. Dürr).

Photochromism Based on Pericyclic Reactions: Cycloaddition Reactions


Cycloaddition reactions involving 4n electrons: (2+2) cycloaddition;
photochemical energy storage systems based on reversible valence
photoi somerization (G. Jones II).
Cycloaddition re.actions involving 4n electrons:(2+2) cycloaddition;
molecules with multiple bonds ingorporated in or linked 10 aromatic
systems (J-P. Desvergne, H. Bouas-Laurent).
Cycloaddition reactions involving 4n electrons: (4+4) cycloaddition
reactions between unsaturated conjugated systems (H. Bouas-Laurent, J-P. Desvergne).
Cycloaddition reactions involving 4n+2 electrons. photochromism based
on the reversible reagtion of singlet oxygen with aromatic compounds (H.-D. Brauer, R. Schmidt).

Photochromism Based on Tautomerism (Hydrogen Transfer)

Tautomerism by hydrogen transfer in salicylates, triazoles and
oxazoles (H.E.A. Kramer).
Tautomerism by hydrogen transfer in anils, aci-nitro and related
compounds (E. Hadjoudis).


Photochromism Based of Dissociation Processes

Photochromism based on dissociation processes(R. Aldag).

Photochromism in Biological Systems

Phytochrome (S.E. Braslavsky).
Retinal proteins (F. Siebert).


Environmental Effects on Organic Photochromic Systems

Environmental effects on organic photochromic systems (V.A. Krongauz).


The Use of Silver Salts for Photochromic Glasses

The use of silver salts for photochromic glasses (H.J. Hoffmann).
Applications
Spiropyrans and related compounds (R. Guglielmetti).
Spirooxazines (N.Y.C. Chu).
Actinometry (G. Gauglitz).
Photochromic materials and photoresists (K. Ichimura).

New Developments Highly Promising for Applications

Photochromism by orientation (J. Michl).
S Pectral hole - burning (U.P. Wild and A. Renn).
Bacteriorhodopsin and its functional variants: potential
applications in modern optics (N. Hampp, C. Bräuchle).
SUBJECT Photochemistry
BOOK SERIES
SUPER AREA Chemistry and Chemical Engineering


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